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Beilstein J. Org. Chem. 2019, 15, 285–290, doi:10.3762/bjoc.15.25
Graphical Abstract
Scheme 1: Typical syntheses of 1,2-divinylcyclopropanes and rationale hypothesis for their syntheses from cyc...
Scheme 2: Synthesis of 1,2-divinylcyclopropane 3a: Optimization studies. aIsolated yield. bDetermined by 1H N...
Scheme 3: Synthesis of 1,2-divinylcyclopropanes 3 from cyclopropenes 1 and unbiased 1,3-dienes 2: Scope. (Yie...
Scheme 4: Rh-catalyzed intramolecular cyclopropanation with dienylcyclopropene 4 (the trans/cis ratio is rela...
Scheme 5: Zn- or Rh-catalyzed reactions of cyclopropenes 1 with furan (6) and 1,4-cyclohexadiene (8) and comp...